ISO 4277:1977

Cryolite, natural and artificial — Conventional test for evaluation of free fluorides content

Publication date:   Nov 1, 1977

95.99   Withdrawal of Standard   Jan 15, 2004

General information

95.99   Withdrawal of Standard   Jan 15, 2004

ISO

ISO/TC 226 Materials for the production of primary aluminium

International Standard

71.060.50   Salts

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Scope

Applicable to products having contents of AlF3 of more than 0.15 % (m/m) or of NaF of more than 0.4 % (m/m). Covers sintering of a test portion with a known quantity of sodium fluoride in a muffle furnace at a temperature of (790 10) °C. Under these conditions, aluminium fluoride in excess of that required by the stoichiometric formula AlF3 .3NaF reacts to form cryolite; extraction of the ground sintered mass with boiling water. Acidification with hydrochloric acid solution to a pH less than 3.7 and titration of the excess sodium fluoride with thorium nitrate solution in the presence of alizarin-S as indicator. Has also been approved by the IUPAC.

Life cycle

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WITHDRAWN
ISO 4277:1977
95.99 Withdrawal of Standard
Jan 15, 2004