ISO 16666:2025

Surface chemical analysis — Total reflection X-ray fluorescence — Principles and general requirements ISO 16666:2025

Publication date:   Nov 7, 2025

General information

60.60   Standard published   Nov 7, 2025

ISO

ISO/TC 201/SC 10 X-ray Reflectometry (XRR) and X-ray Fluorescence (XRF) Analysis

International Standard

71.040.40   Chemical analysis

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Scope

The document provides the physical principles and specifies instrumental requirements for total reflection X‑ray fluorescence analysis (TXRF) spectrometers. This document specifies general procedures for calibration, method development and verification of TXRF measurements and quality control.
The document describes measurements with TXRF conditions having a fixed glancing angle below the critical angle of total reflection and considerably enhanced excitation radiation intensity. Although certain definitions of grazing incidence geometry are shown for clarification, this document is not applicable to measurement setups working under such conditions.

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ISO 16666:2025
60.60 Standard published
Nov 7, 2025




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