EN ISO 6923:2024

Paints and varnishes - Determination of monomeric diisocyanate content in coating materials and similar products using high performance liquid chromatography with ultraviolet detection (HPLC-UV) (ISO 6923:2023)

Publication date:   Aug 19, 2024

General information

60.60   Standard published   Jun 12, 2024

CEN

CEN/TC 139 Paints and varnishes

European Norm

87.040   Paints and varnishes

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Scope

This document specifies a method for the quantitative determination of monomeric diisocyanate content in coating materials, adhesives and other liquid or pasty materials.
This method is suitable for the quantification of the following monomeric diisocyanates: methylene diphenyl diisocyanate (MDI, 2,4’-MDI and 4,4’-MDI), toluene diisocyanate (TDI, 2,6-TDI, 2,4-TDI), (cis/trans) isophorone diisocyanate (IPDI) and hexamethylene diisocyanate (HDI,1,6-HDI) in various matrices for concentrations ranging from 0,01 % to 2,0 % mass fraction. For higher concentrations, a suitable dilution before the derivatization with p-nitrobenzyl-N-propylamine (PNBPA) is performed. The measurements are carried out using ultra high performance liquid chromatography (UHPLC) with a multiple wavelength detector.

Life cycle

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PUBLISHED
EN ISO 6923:2024
60.60 Standard published
Jun 12, 2024

Relations

Adopted from ISO 6923:2023 IDENTICAL